Both sides continue to prepare for the 2018 World Cup in Russian Federation this summer.
Without waiting to be substituted, the injury-prone Kompany walked off shortly after the break after appearing to overstretch while making a defensive challenge. The central defender hurt himself when he lunged for the ball and nearly immediately left the pitch.
The Manchester City defender's career has been blighted by injuries, but he appeared fit ahead of the pre-World Cup friendly at the King Baudouin stadium.
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Portugal star striker Cristiano Ronaldo did not feature in the game against the Red Devils.
Belgium will play Panama, Tunisia and England in Group G, while European Champions Portugal will face Spain, Morocco and Iran in Group B.
Belgium opened strongly, outplaying Portugal in the midfield, but could not turn its pressure into a goal.
Jan Vertonghen, already Belgium's most-capped player, made his 100th appearance for the national team, the Tottenham centre-back lining up in Roberto Martinez's back line, but the coach will be concerned about Kompany after he was substituted early in the second half.
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Vertonghen nearly marked his 100th appearance with a lovely strike, but when he collected a lay-off from Marouane Fellaini and fired at goal, Beto made a fine flying save high to his right.
In terms of chances there remained little to write home about, with Martins only managing to loop a good chance over the bar after meeting Silva's cut-back from the right, whilst Thomas Meunier's cross-shot was well dealt with at the other end.
"It wasn't bad, but we could do better", De Bruyne said.
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